You become friends with the sexy co-worker and decide to carpool to work together. You're married, or engaged, or you're in a committed relationship. All those tingly feelings and the fantasies that perhaps a "perfect love" can really exist isn't destiny knocking -- they're caused by "love chemicals" in your brain.
You become "friends" with an ex on Facebook and reminisce about the past. You spend hours thinking about them and your heart races whenever you see a text from them. You tell yourself it's ok because you're not really cheating, you're just chatting. Biochemical research has shown that the effect of these love chemicals is twofold: they are released in response to your friend, and they bond you to him or her.
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In truth, most infidelity occurs not because it is planned, but because people find themselves in situations where their emotions completely overwhelm (and even surprise) them.